Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 10, Pages 1573-1576Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc06258a
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Funding
- National Natural Science Foundation of China [22003008]
- Science and Technology Commission of Shanghai Municipality [19YF1400400]
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In the corner-opening and corner-capping reactions of monosubstituted T-8 POSS, the yield of monosubstituted T-8 POSS is much higher than the ortho- and meta-isomers of disubstituted T-8 POSS, and the para-isomer is negligible.
We applied chromatographic and spectroscopic techniques to revisit the product distribution of the corner-opening and corner-capping reactions of monosubstituted T-8 POSS. The monosubstituted Si is more likely to be removed than the remaining seven Si atoms during the corner-opening. After the corner-capping, the yield of monosubstituted T-8 POSS is much higher than the yields of the ortho- and meta-isomers of disubstituted T-8 POSS, and the para-isomer is negligible.
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