Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 3, Pages 395-398Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc06144e
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Funding
- Julius-Maximilians-Universitat Wurzburg
- China Scholarship Council (CSC)
- Alexander von Humboldt Foundation
- National Natural Science Foundation of China [21901114]
- Natural Science Foundation of Jiangsu Province [BK20180685]
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A Cu-catalysed borylation reaction can achieve high-yield synthesis of arylboronic esters from aryl alkyl sulfones, while selective cleavage of cyclic sulfones can be achieved through Cu-mediated or Cu-free processes to prepare sulfonyl-containing boronate esters.
A Cu-catalysed borylation of aryl alkyl sulfones was developed for the high yield synthesis of versatile arylboronic esters using a readily prepared NHC-Cu catalyst. In addition, the selective cleavage of either alkyl(C)-sulfonyl or aryl(C)-sulfonyl bonds of a cyclic sulfone via Cu-free or Cu-mediated processes generates the corresponding sulfinate salts, which can be further derivatised to provide sulfonyl-containing boronate esters, such as sulfones and sulfonyl fluorides.
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