4.7 Article

Copper(ii)-photocatalyzed decarboxylative oxygenation of carboxylic acids

Journal

CHEMICAL COMMUNICATIONS
Volume 58, Issue 28, Pages 4456-4459

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2cc00570k

Keywords

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Funding

  1. Deutsche Forschungsgemeinschaft [RE948/18-1, RE3630/5-1]
  2. Fonds der Chemischen Industrie
  3. BioLEC, an Energy Frontier Research Center - U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0019370]

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The study showcases the concept of light-induced homolysis for radical generation in Cu-II-photocatalyzed decarboxylative oxygenation. Two Cu-II-carboxylate complexes with different coordination geometries were synthesized and characterized by X-ray analysis, correlating their structure with their ability to initiate light-induced decarboxylations.
Showcasing the concept of light-induced homolysis for the generation of radicals, the Cu-II-photocatalyzed decarboxylative oxygenation of carboxylic acids with molecular oxygen as the terminal oxidant is described. Two Cu-II-carboxylate complexes with different coordination geometries were synthesized and characterized by X-ray analysis, correlating their structure with their ability to initiate light-induced decarboxylations.

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