4.7 Article

An ultralow-acceptor-content supramolecular light-harvesting system for white-light emission

Journal

CHEMICAL COMMUNICATIONS
Volume 58, Issue 14, Pages 2343-2346

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc06647a

Keywords

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Funding

  1. National Natural Science Foundation of China [21702020]
  2. China Scholarship Council [202008320118]
  3. Engineering and Physical Sciences Research Council [EP/R512461/1]
  4. Marie Sklodowska-Curie Fellowship [845640]
  5. Marie Curie Actions (MSCA) [845640] Funding Source: Marie Curie Actions (MSCA)

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Researchers have successfully developed a novel material that can self-assemble into dispersed nanoparticles in water and achieve efficient white-light emission through a light-harvesting strategy. By co-assembling with cyanostilbene, the material shows potential for application in white-light encryption materials.
White-light emission in donor-acceptor systems usually requires relatively high acceptor content and/or multiple acceptors to neutralize the primary color of donors. Herein, a cyanostilbene-bridged ditopic ureidopyrimidinone donor (CSU) was designed and synthesized, which can self-assemble into dispersed nanoparticles in water. Fascinatingly, efficient white-light emission can be realized by co-assembling 0.1% DBT into the nanoparticles through a light-harvesting strategy. This new system is further demonstrated for use in white-light encryption materials.

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