Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 7, Pages 1041-1044Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc06098h
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Funding
- National Natural Science Foundation of China [22077018]
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Through systematic optimization of ligand structures and reaction conditions, we successfully report a room-temperature Pd-catalyzed methoxy-carbonylation with high branched selectivity. The strategic design of the new class of bisphosphine-picolinamide ligands enabled the synthesis of various alpha-substituted acrylates in good to excellent yields.
We report the room-temperature Pd-catalyzed methoxy-carbonylation with high branched selectivity using a new class of bisphosphine-picolinamide ligands. Systematic optimization of ligand structures and reaction conditions revealed the significance of both the picolinamide and bisphosphine groups in the ligand backbone. This strategic design of ligand was leveraged to deliver various alpha-substituted acrylates in good to excellent yields.
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