4.7 Article

Bi/trinuclear Pt1,2Cu cluster assembly from isolated metal atoms

Journal

CHEMICAL COMMUNICATIONS
Volume 58, Issue 26, Pages 4176-4179

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc06838e

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Funding

  1. National Natural Science Foundation of China [21932005, 22172164]
  2. State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics
  3. National Institute of General Medical Sciences-NIGMS from the National Institutes of Health [5 P30 GM110758-02]
  4. National Institutes of Health

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A facile strategy for synthesizing uniform heterometallic bi/tri-atom clusters starting from mono-metallic atoms in the liquid phase is reported. Specifically, Pt1,2Cu bi/tri-atoms are prepared by reducing CuCl2 at preformed Pt-1 atoms with ethanol inside a PDMS-PEG protective layer. The metal atoms in the Pt1,2Cu clusters are in reduced chemical states.
We report a facile strategy for synthesizing uniform heterometallic bi/tri-atom clusters starting from mono-metallic atoms in the liquid phase. Specifically, Pt1,2Cu bi/tri-atoms are prepared by reducing CuCl2 at preformed Pt-1 atoms with ethanol inside a PDMS-PEG protective layer. The metal atoms in the Pt1,2Cu clusters are in reduced chemical states.

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