Journal
CHEMICAL COMMUNICATIONS
Volume 58, Issue 22, Pages 3637-3640Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cc07127k
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Funding
- National Natural Science Foundation of China [21971182, 21771131]
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In this study, a catalyst-free visible-light-driven C(sp(2))-H arylation of unprotected phenols with arylbromides was developed to obtain 2-arylated phenols. This reaction occurs through the excitation of an electron donor-acceptor complex between a phenolate and an arylbromide, electron transfer, and debrominative C(sp(2))-C(sp(2)) coupling.
We have developed a catalyst-free visible-light-driven C(sp(2))-H arylation of unprotected phenols with arylbromides to give 2-arylated phenols. This reaction proceeds through the excitation of an electron donor-acceptor complex between a phenolate and an arylbromide, electron transfer, and debrominative C(sp(2))-C(sp(2)) coupling.
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