Effects of molten salt temperature and holding time on synthesis of hercynite by molten salt method

Taking flake alpha-Al2O3, Fe2O3 and graphite as raw materials and KCl-K2SO4 as molten salt medium, the effects of different molten salt temperature and holding time on the synthesis of hercynite by the molten salt method were studied. The results shows that the content of hercynite increases with the increase of molten salt temperature and holding time, and the optimum process condition for synthesis hercynite from KCl-K2SO4 molten salt is holding at 1000 ? for 6 h. Meanwhile, the micro-morphology of the synthesizes hercynite powder is independent of the micro-morphology of the raw material, indicating that the process of synthesizing hercynite with KCl-K2SO4 as molten salt medium is dominated by the dissolution-precipitation mechanism.

Automated summary

This study investigated the synthesis of hercynite using the molten salt method with different molten salt temperatures and holding times. The results showed that the content of hercynite increased with higher temperatures and longer holding times, and the optimal conditions were determined. Additionally, the morphology of the synthesized hercynite powder was independent of the raw material, indicating the dominance of a dissolution-precipitation mechanism in the synthesis process.