4.7 Article

Performance evaluation of basalt fiber-reinforced geopolymer composites with various contents of nano CaCO3

Journal

CERAMICS INTERNATIONAL
Volume 47, Issue 21, Pages 29949-29959

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2021.07.169

Keywords

Basalt fibers; Geopolymer; Nano CaCO3; Compressive strength; Fracture toughness; Scanning electron microscopy

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The study investigated the mechanical performance of basalt fiber-reinforced fly ash-based geopolymer pastes with varying contents of nano CaCO3. Results showed that 3% nano CaCO3 improved compressive strength and hardness, while 2% nano CaCO3 enhanced flexural strength, impact strength, and fracture toughness of the composite paste. SEM analysis indicated that nano CaCO3 addition improved microstructure and densification of geopolymer paste.
High carbon footprint of cement production is the major drawback of plain cement concrete resulting in environmental pollution. Geopolymer composites paste can be effectively used as an alternative to Portland cement in the construction industry for a sustainable environment. The demand for high-performance composites and sustainable construction is increasing day by day. Therefore, the present experimental program has endeavored to investigate the mechanical performance of basalt fiber-reinforced fly ash-based geopolymer pastes with various contents of nano CaCO3. The content of basalt fibers was fixed at 2% by weight for all specimens while the studied contents of nano CaCO3 were 0%, 1%, 2%, and 3%, respectively. The compressive strength, compressive stress-strain response, flexural strength, bending stress-strain response, elastic modulus, toughness modulus, toughness indices, fracture toughness, impact strength, hardness, and microstructural analysis of all four geopolymer composite pastes with varying contents of nano CaCO3 using scanning electron microscopy (SEM) were evaluated. The results revealed that the use of 3% nano CaCO3 in basalt fiber-reinforced geopolymer paste presented the highest values of compressive strength and hardness while the use of 2% nano CaCO3 showed the highest values of flexural strength, impact strength, and fracture toughness of composite paste. The SEM results indicated that the addition of nano CaCO3 improved the microstructure and provided a denser geopolymer paste by refining the interfacial zones and accelerating the geopolymerization reaction.

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