Effects of TeO2/B2O3 substitution on synthesis, physical, optical and radiation shielding properties of ZnO-Li2O-GeO2-Bi2O3 glasses

Tellurite glass is a model material having superior features for several applications. It can be considered as a potential host matrix for different oxides, and this paper aims to study the effects of TeO2/B2O3 substitution on synthesis, physical, optical and radiation shielding properties of ZnO-Li2O-GeO2-Bi2O3 glasses produced by melt quenching technique. The physical and optical features of the fabricated glasses were experimentally investigated by determining pivotal parameters such as density, XRD, tellurium ion concentration (N-i), linear refractive index (n(o)), polaron radius (r(p)) and inter nuclear distance (r(i)). Moreover, the relative radiation deposition within the glasses was assessed via the attenuation coefficients (e.g. MAC), specific gamma ray constant (r), total stopping power (TSP), neutron cross sections, and dose rate (D). Our results suggest that both TeO2 and B2O3 additives have a significant effect on the fundamental properties of the ZnO-Li2O-GeO2-Bi2O3 glasses. It also found that the lower thicknesses of the present glasses are required to provide the same level of shielding than ordinary, ilmenite, steel scrap, hematic-serpentine, ilmenite-limonite and basalt-magnetite concretes, RS253-G18 and RS360 glass shields. Therefore, presently investigated glasses are promising photon shields in different technological applications of gamma- and x-rays.

Automated summary

Tellurite glass is studied for its potential as a host matrix for different oxides in ZnO-Li2O-GeO2-Bi2O3 glasses. The effects of TeO2/B2O3 substitution on synthesis, physical, optical, and radiation shielding properties were investigated. The results show that TeO2 and B2O3 additives significantly impact the fundamental properties of the glasses.