4.7 Article

Enhanced thermoelectric properties of tungsten oxide-reduced graphene oxide nanocomposites

Journal

CERAMICS INTERNATIONAL
Volume 47, Issue 19, Pages 27885-27889

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.ceramint.2021.06.218

Keywords

WO3; Reduced graphene oxide; Thermoelectrics; Nanocomposites

Funding

  1. Ministry of Electronics and Information Technology (MeitY) through NNetRA Project [RP03530]
  2. Department of Science and Technology (DST) through NNetRA Project [MI01756]
  3. Council of Scientific and Industrial Research (CSIR)

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This article synthesized tungsten oxide nanoparticles and tungsten oxide-reduced graphene oxide nanocomposites, and studied their thermoelectric properties. The results showed that the thermoelectric material figure of merit of WO3-rGO nanocomposites increased by 8.8 times at 313K, with significantly enhanced electrical conductivity and reduced thermal conductivity compared to WO3 nanoparticles.
Metal oxide as a thermoelectric material has shown great attention in recent years due to its outstanding thermal and chemical stability, good oxidation resistance, low cost, etc. This article reports the successful synthesis of tungsten oxide (WO3) nanoparticles and tungsten oxide-reduced graphene oxide (WO3-rGO) nanocomposites and studies of their thermoelectric properties. The structural characteristics of the WO3 nanoparticles and WO3-rGO nanocomposites were examined using XRD and Raman techniques. At 313 K, WO3-rGO nanocomposites exhibit an - 8.8 times enhancement in the thermoelectric material figure of merit (zT). These excellent performances are further supported by up to - 13.7 times enhanced electrical conductivity and a - 56% reduction in thermal conductivity compared to WO3 nanoparticles. It has been concluded that reduce graphene oxide helps in forming a conducting pathway in the WO3-rGO nanocomposites, allowing the easy passage of charge carriers in the matrix.

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