4.7 Article

Recovery and direct carbonation of brucite from desalination reject brine for use as a construction material

Journal

CEMENT AND CONCRETE RESEARCH
Volume 152, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.cemconres.2021.106673

Keywords

Brucite; Reject desalination brine; Chemical precipitation with calcium oxide (CaO); Strength development; Carbon dioxide (CO2) sequestration

Funding

  1. Abu Dhabi Department of Education and Knowledge (ADEK) [ADHPG-RA686]
  2. NYUAD Center for Interacting Urban Networks (CITIES) - Tamkeen under the NYUAD Research Institute [CG001]
  3. Swiss Re Institute under the Quantum CitiesTM initiative

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The study investigated the direct carbonation of brucite recovered from reject brine and observed significant improvement in mechanical properties post-carbonation. Findings suggest that cost-effective synthesis of brucite from reject brine could sequester CO2, making it a promising material for the construction industry.
This study investigated the direct carbonation of brucite recovered from reject brine of desalination plants and its mechanical property development as part of an assessment for its potential use as a construction material. Brucite nano-powder was synthesized from reject brine through chemical precipitation with calcium oxide (CaO). Formation of brucite with nano-platelet-like structures was observed. Compacted pellets produced with the brucite precipitates and exposed to 20% carbon dioxide (CO2) attained a 4-fold increase in the compressive strength (similar to 30 MPa) within one day relative to those cured under the ambient condition. Thermogravimetry and morphological analyses of fragments extracted from the carbonated pellets revealed the formation of amorphous hydrated magnesium carbonates, which contributed to the matrix densification and strength gain. The findings confirm that brucite can be synthesized from reject brine with low-cost and energy-effective procedures and has the capability to sequester CO2, making it a promising and sustainable material for the construction industry.

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