In situ TEM observation of calcium silicate hydrate nanostructure at high temperatures

Fire poses a substantial threat to concrete structures because calcium silicate hydrate (C-S-H) is not thermally stable at high temperatures. Herein, in situ TEM at temperatures from 20 to 800 degrees C was conducted to study the thermal-induced structural changes in C-S-H. We captured C-S-H shrinks at an average rate of 0.02 mu m(2)/degrees C upon heating with three stages observed, including induction, constant, and rapid periods. Our observation revealed that an 800 nm pore could be healed during pore structure evolution owing to the reconstruction and deformation among C-S-H blocks. The Ca/Si ratio was dropped at higher temperatures because of the leakage of calcium ions from the C-S-H structure to form CaO precipitates. The temperature-driven phase transformation and degradation were also detected using electron diffraction that C-S-H was transformed into metastable calcium silicate minerals above 800 degrees C. This work provides insights into the nanoscale transformation of C-S-H at high temperatures.

Automated summary

In situ TEM study shows that C-S-H shrinks at high temperatures, with a decrease in Ca/Si ratio leading to the formation of CaO precipitates. Moreover, above 800 degrees C, C-S-H undergoes phase transformation into metastable calcium silicate minerals.