Journal
CELLULOSE
Volume 29, Issue 3, Pages 1647-1666Publisher
SPRINGER
DOI: 10.1007/s10570-021-04369-6
Keywords
Silk fibroin (SF); Poly(vinyl alcohol) (PVA); TEMPO-oxidized bacterial cellulose nanofiber (TBC); Silver nanoparticles (AgNPs); Bio-nanocomposite film; Mechanical properties; UV shielding; Antibacterial
Funding
- China Scholarship Council [201908370222]
- Natural Science Foundation of Jiangsu Province [BK20201216]
- High Education Science Foundation of Jiangsu Province [19KJD540001]
- Qinglan Project of the Jiangsu Higher Education Institutions of China [3]
- North Dakota State University
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A bio-nanocomposite material consisting of silk fibroin/polyvinyl alcohol as the matrix, TEMPO-oxidized bacterial cellulose nanofiber as the reinforcement, and silver nanoparticles as an antibacterial agent was synthesized. The mechanical and chemical properties of the material can be tailored by adjusting the content of bacterial cellulose nanofiber. The material also exhibits strong UV shielding property, antibacterial activities, and low silver leakage.
Silk fibroin (SF) has been intensively studied as a biobased renewable material for biomedical and other applications. However, its relatively low mechanical properties have limited its use in the applications where an improved strength and structural integrity are desired. In this work, a bionanocomposite material consisting of SF/polyvinyl alcohol (PVA) as the matrix, TEMPO-oxidized bacterial cellulose nanofiber (TBC) as the reinforcement, and silver nanoparticles (AgNPs) as an antibacterial agent, was facilely synthesized. SF also functioned as a reducing agent and TBC as an immobilization template during the in-situ synthesis of AgNPs. It was found that TBC and AgNPs were homogeneously dispersed in the nanocomposites after the synthesis, which led to outstanding mechanical properties of the materials. The mechanical properties, hydrophobicity, and water vapor barrier property of the materials could be tailored by adjusting the content of TBC. Moreover, the bio-nanocomposite films exhibited strong UV shielding property, antibacterial activities and low silver leakage. These properties make the SF/PVA/AgNPs/TBC bio-nanocomposites promising materials for active food packaging and seed storage/packaging applications. [GRAPHICS] .
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