Journal
CATALYSIS LETTERS
Volume 152, Issue 8, Pages 2445-2456Publisher
SPRINGER
DOI: 10.1007/s10562-021-03827-x
Keywords
Graphene oxide; Epoxidation; Heterogeneous catalyst; Magnetite; Mn-porphyrin; Nanoparticle; UHP
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Funding
- Yazd University Research Council
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In this study, manganese porphyrin catalyst was successfully anchored onto magnetite-modified graphene oxide nanosheets and used for efficient epoxidation of alkenes, showing high selectivity and remarkable turnover frequency.
In this research, beta-tetra-brominated meso-tetraphenylporphyrinatomanganese(III) acetate [MnTPPBr4(OAc)] (MnPor) was anchored onto a magnetite imidazole-modified graphene oxide nanosheet (Fe3O4.GO.Im). The obtained catalyst (Fe3O4.GO.Im@MnPor) was characterized through Fourier transform infrared (FT-IR) and diffuse reflectance UV-Visible spectrophotometry (DR UV-Vis), powder X-ray diffractometry (XRD), field emission scanning electron microscopy (FESEM), energy dispersive X-ray (EDX) spectroscopy, thermogravimetric analysis (TGA) and atomic absorption spectroscopy. The characterization was performed to determine the amount of manganese porphyrin loaded on the GO support. The new immobilized catalyst was employed for the efficient epoxidation of different alkenes with urea hydrogen peroxide (UHP) and acetic acid (HOAc) as oxidant activators under mild conditions. Olefins were oxidized efficiently to their corresponding epoxide with 63-100% selectivity in the presence of Fe3O4.GO.Im@MnPor. Moreover, an remarkable turnover frequency (93) was achieved for the oxidation of alpha-pinene. The graphene oxide-bound Mn-porphyrin was recovered from the reaction mixture by magnetic decantation and reused several times. [GRAPHICS] .
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