4.6 Article

Combustion method combined with sonochemical step for synthesis of maghemite-supported catalysts for the hydrogenation of 2,4-dinitrotoluene

Journal

CATALYSIS COMMUNICATIONS
Volume 159, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.catcom.2021.106342

Keywords

Toluenediamine; Maghemite; Sonochemistry; Catalyst; Hydrogenation

Funding

  1. European Union
  2. Hungarian State
  3. European Regional Development Fund [GINOP-2.3.4-15-2016-00004]

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Maghemite particles were synthesized using a combination of combustion method and sonochemical step for preparation of Pt and Pd supported catalysts. The most active catalysts were Pd/maghemite and bimetallic Pd-Pt/maghemite, which were easily separable post-reaction due to their magnetic properties. These catalysts were immediately ready for use in 2,4-dinitrotoluene hydrogenation to produce 2,4-toluenediamine.
Maghemite particles were synthesized by using a combined combustion method and sonochemical step. Maghemite was used as carrier to prepare supported Pt and Pd catalysts after deposition via a sonochemical step. The catalysts were immediately ready to be used (metals were catalytically active) for the 2,4-dinitrotoluene hydrogenation to produce 2,4-toluenediamine. The most active catalysts were the Pd/maghemite and bimetallic Pd-Pt/maghemite. The catalysts were easily separable after reaction due to their magnetic properties.

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