4.8 Article

Anisotropic friction behavior of aligned and oriented graphite flakes/copper composite

Journal

CARBON
Volume 186, Issue -, Pages 64-74

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2021.09.074

Keywords

Composite; Graphite; Orientation; Friction; Transition

Funding

  1. National Key R&D Program of China [2017YFB0310300, 2017YFB0903803]
  2. National Natural Science Foundation of China [51672209]
  3. Shaanxi Innovation Capacity Support Program [2018TD-031]
  4. Natural Science Basic Research Plan inShaanxi Province of China [2016JQ5046]

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This study prepared and tested graphite flakes/copper composites with specific dihedral angles, showing an increase in friction coefficient with larger dihedral angles due to adhesion, and a decrease due to ploughing. The friction coefficients were lower at 30 to 60 degrees, and the wear rate decreased monotonically as the dihedral angle increased.
Graphite flakes as lubricant are widely used for friction materials, but little is known about the friction behavior at sliding surface oriented at some angle to the basal plane of graphite. In this paper, oriented graphite flakes/copper (volume ratio of 7/3) composite was prepared by vacuum hot-pressing sintering. The friction coefficient evolution of the composite with the dihedral angle (4) between sliding surface and graphite basal plane was estimated based on the numerical solutions of the anisotropic stiffness at the contact plane, and measured experimentally. Theoretical estimates suggested an increase of the friction coefficient induced by adhesion with raising the dihedral angle, and a decreased one caused by ploughing. A pronounced trend of the former happened with the dihedral angles of more than 75 degrees, while for the latter it was conspicuous with the dihedral angles of less than 15 degrees. Through ball-on-disk friction experiments, the friction coefficients were fairly low with the dihedral angles from 30 degrees to 60 degrees, which was consistent with the theoretical prediction, and a monotonous decrease of the wear rate was exhibited with increasing the dihedral angle due to increased shear modulus and hardness. This anisotropic friction behavior may provide new ideas for the designs of friction materials. (C) 2021 Elsevier Ltd. All rights reserved.

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