Journal
CARBON
Volume 185, Issue -, Pages 215-223Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.carbon.2021.08.056
Keywords
Carbon nanotube; Silicon; Heterojunction solar cell; Molybdenum oxide; Thermal annealing
Funding
- State Scholarship Fund of the China Scholarship Council [201806380052]
Ask authors/readers for more resources
A multifunctional MoOx layer was utilized to enhance the size and performance of CNT/Si heterojunction solar cells, providing a facile route for practical application.
Carbon nanotube (CNT)/silicon heterojunction solar cells have been extensively studied owing to the ease of junction fabrication. Encouraging power conversion efficiencies (PCEs) have been reported; however, many of them are limited to small cells (<1 cm(2)). Herein, we report MoOx as a multifunctional layer that enables the size and performance enhancement. A 4 cm(2)-sized MoOx-CNT/n-Si solar cell with a PCE of 10.0% was realized via simple processes: dispersion-filtration-transfer for the CNT layer, hot-wire oxidation-sublimation deposition for the MoOx layer, mask-deposition for the Ag grid electrodes, and spin-coating for the polymethyl methacrylate anti-reflective layer. The MoOx layer played an essential role as a blocking layer to prevent direct contact and current leakage between Ag and n-Si while allowing the electrical conduction between Ag and CNT. It also served as a p-type dopant for the CNTs, which enhanced the electrical conduction and separation of electron-hole pairs at the heterojunction, and as an enhancer for the anti-reflective effect of the MoOx-CNT layer. Post-thermal annealing of MoOx was found to be crucially important, and the role of MoOx was also evaluated. This combination of a multifunctional MoOx layer with a metal grid electrode provides a facile route for practical CNT/Si heterojunction solar cells. (C) 2021 The Author(s). Published by Elsevier Ltd.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available