Eco-friendly and superhydrophobic nano-starch based coatings for self-cleaning application and oil-water separation

High-performance nano-based superhydrophobic coatings have attracted tremendous attention in a wide range of sectors. As a biodegradable and low-cost natural polymer, starch nanoparticles (SNPs) exhibit significant potential for use in many advanced materials. However, nano-starch based superhydrophobic coatings have not yet been reported. Herein, SNPs/polydimethylsiloxane composites were applied to fabricate these coatings using an environmentally friendly approach. The coating exhibited superhydrophobic (water contact angle 152.0 degrees and sliding angle <9.0) and self-cleaning properties owing to the hierarchical micro and nanostructures formed by coralloid SNP aggregates combined with the low surface energy of the PDMS covering. Meanwhile, the strong adhesion of PDMS and chemical bonding of SNPs with PDMS endowed the coatings with mechanical and chemical robustness. The excellent oil-water separation abilities of the coating were also comprehensively confirmed. This coating shows the potential application in the development of eco-friendly self-cleaning materials and oily wastewater treatment.

Automated summary

Nano-starch and polydimethylsiloxane composite coatings exhibit superhydrophobic and self-cleaning properties with excellent mechanical and chemical robustness, suitable for oil-water separation and oily wastewater treatment applications.