Nanoparticles-doped induced defective ZIF-8 as the novel cathodic luminophore for fabricating high-performance electrochemiluminescence aptasensor for detection of omethoate

Although the use of omethoate (OMT) for pests control is enormously economically beneficial for agricultural production, the high toxicity of OMT to nontarget organisms has resulted in the contamination of soil, river water, and food materials. Developing sensitive and convenient techniques to detect OMT residues is vital to society. Electrochemiluminescence (ECL) is a powerful analytical tool and has been widely applied in biosensors. To boost the co-reaction efficiency and ECL intensity, we introduced defective ZIF-8 as the novel cathodic luminophore. At the same time, defect generated by the doping of MoTe2 nanoparticles into ZIF-8 could easily electrocatalytic reduce the co-reactor S2O82- to SO4 center dot-. Hence, based on the catalysis of defective ZIF-8, the ECL intensity of MoTe2/ZIF-8 nanocomposites is much higher than both ZIF-8 and MoTe2 nanoparticles. By integration of as-prepared materials with specificity omethoate aptamer, the ECL sensor showed a broad linear range (10 10 g L-1 and 10 5 g L-1) and a comparatively low detection limit (3.3 x 10(-11) g L-1). Besides, the ECL aptasensor appeared a good practical performance to detect potato and spinach extraction samples, which proposed a promising guideline for developing ECL aptasensors with high efficiency.

Automated summary

Introducing defective ZIF-8 to enhance ECL intensity and preparing efficient ECL sensor with MoTe2 nanoparticles and ZIF-8 composites for detecting omethoate residues, which has broad linear range and low detection limit.