Journal
APPLIED SURFACE SCIENCE
Volume 563, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.apsusc.2021.150280
Keywords
Lithium-ion batteries; Anode; Silicon; Waste glass; Si-C covalent bond
Categories
Funding
- National Natural Science Foundation of China [51974208, 52002297, U2003130]
- Natural Science Funds of Hubei Province for Distinguished Young Scholar [2020CFA099]
- Major Project of Technology Innovation of Hubei Province [2018AAA011]
- Project of Natural Science Foundation of Hubei Province [2019CFB204]
- Special Project of Central Government for Local Science and Technology Development of Hubei Province [2019ZYYD024]
- Innovation Group of Natural Science Foundation of Hubei Province [2019CFA020]
- City University of Hong Kong Strategic Research Grants [7005505]
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A simple and eco-friendly method was used to prepare Si/carbon nanotube composites with strong Si-C covalent bonding, resulting in excellent specific capacity and cycling stability for high-energy lithium-ion batteries. The composites exhibit potential as anode materials due to their low cost and controllable preparation process.
Silicon is regarded to be promising anode materials in next-generation rechargeable lithium-ion batteries due to the high theoretical capacity and natural abundance. In order to overcome intrinsic drawbacks such as the low conductivity and unstable solid electrolyte interface film, different Si and carbon (C) nanocomposites have been designed but they are often plagued by the complex structural design, high preparation cost, and weak interactions between C and Si resulting in limited electrochemical performance. Herein, a facile, eco-friendly, lowcost, and controllable route is described to prepare Si/carbon nanotube composites with strong Si-C covalent bonding from recycled waste glass and commercial carbon nanotubes (g-Si/CNTs) via simple mechanical ball milling and magnesiothermic reduction (MR). Owing to the conductive CNTs network, strong Si-C covalent bonds are formed in situ between the CNTs and Si nanoparticles and consequently, the g-Si/CNTs electrode shows an excellent specific capacity of -895 mAh g-1 as well as 84.3% capacity retention at 0.1 A g-1 after 200 cycles. The g-Si/CNTs composite produced from recycled waste glass has large potential as anode materials in highenergy lithium-ion batteries.
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