Journal
APPLIED SURFACE SCIENCE
Volume 565, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.apsusc.2021.150582
Keywords
1T-MoS2; Ternary composite; Polyaniline; Graphene; Fluoroethylene carbonate; Lithium-ion battery
Categories
Funding
- Ministry of Science and Technology, Taiwan [MOST 108-2113-M-029 -003, MOST 109-2113-M-029 -004, MOST 109-2811-M-029 -503]
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The ternary composite of MoS2, PANI-rGO, and FEC shows enhanced lithium-ion diffusion and intercalation, as well as improved electron transportation. The addition of 10 wt% FEC into the traditional electrolyte significantly enhances the cyclic stability of the ternary composite, leading to two times higher capacity retention after 400 charge-discharge cycles.
MoS2 has been viewed as a unique anode material for lithium-ion batteries; however, its electrochemical performance is usually restrained by poor conductivity of 2H phase and an uneven solid-electrolyte interphase (SEI). To tackle the above issues, the ternary composite is synthesized by self-assembling MoS2 2D sheets with higher percentage of metallic 1T-phase on polyaniline functionalized reduced graphene oxide (PANI-rGO) through an electrostatic interaction. The flower-like aggregate of 1T-MoS2 having increased interlayer distances is beneficial for diffusion and intercalation of lithium ions. Furthermore, the graphene substrate facilitates the electron transportation. At the current density of 0.1 and 2 A g-1, the ternary composite has the specific capacities of 812 and 333 mAh g-1 respectively. On the other hand, the cyclic stability of ternary composite can be further improved when 10 wt% fluoroethylene carbonate (FEC) is added into the traditional carbonate-based electrolyte. The capacity retention of ternary composite cycled in a FEC-mixed electrolyte is two times higher than that in a traditional electrolyte after 400 charge-discharge cycles. This is attributed to the fact that the use of FEC enables the formation of active LiF-rich SEI.
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