4.6 Article

Phase-field simulation of element distribution and kinetics evolution of Cr/Cu core-shell nanoparticles in Fe-Cr-Al-Cu alloy

Journal

Publisher

SPRINGER HEIDELBERG
DOI: 10.1007/s00339-021-05171-8

Keywords

Core-shell structure; Fe-Cr-Al-Cu; Kinetics; Phase-field

Funding

  1. National Natural Science Foundation of China [51571122]
  2. Fundamental Research Funds for the Central Universities [30921013107]

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Nanoscale Cu clusters and alpha ' phase affect the hardness and brittleness of Fe-Cr-based stainless steel. The separation of Cr-enriched nanoscale alpha ' phase with Cu shell in Fe-Cr-Al-Cu alloys was revealed by three-dimensional phase-field simulation. The influences of Cu content and temperature on the evolution kinetics and element distribution were clarified.
Nanoscale Cu clusters and alpha ' phase affect the hardness and brittleness of Fe-Cr-based stainless steel. The separation of Cr-enriched nanoscale alpha ' phase with Cu shell in Fe-Cr-Al-Cu alloys was revealed by three-dimensional phase-field simulation. The influences of Cu content and temperature on the evolution kinetics and element distribution were clarified. In the phase separation process, the Al is distributed in the matrix, Cu is first distributed in the matrix, then enriched around the Cr-enriched alpha ' phase, forming the nanoscale composite precipitates with Cr/Cu core-shell structure. The Cu shells have a retardant effect on the diffusion of Cr atoms, and the Cu shell becomes wider with the increased Cu content. The high Cu content delays the phase separation, growth, and coarsening kinetics of the alpha ' phase, while high temperature accelerates the phase separation kinetics. The influence of Cu content and temperature on the evolution of Cr/Cu core-shell nanoparticles reveals the complex nanoparticles formation and kinetics evolutions in the Fe-Cr-Al-Cu alloys.

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