Journal
APPLIED CATALYSIS B-ENVIRONMENTAL
Volume 297, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.apcatb.2021.120499
Keywords
MoSx catalyst; co-HDO; Bio-fuels; Oxygen content; Active hydrogen
Funding
- National key R & D program of China [2018YFC1801901]
- Natural Science Foundation of Shandong Province [ZR2019BB050]
- Fundamental Research Funds for the Central Universities of China [18CX02144A, 18CX05024A]
- Benefiting People Special Fund for Qingdao Science and Technology Project [20-3-4-27-nsh]
- Opening Fund of State Key Laboratory of Heavy Oil Processing [SKLOP202003003]
- Special Funds of Taishan Scholars Project of Shandong Province [ts20190919]
- University of Calgary's Canada First Research Excellence Fund, the Global Research Initiative (GRI) for Sustainable Low Carbon Unconventional Resources
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The use of MoSx catalyst can effectively enhance the co-HDO reaction by promoting oxygen transfer, leading to bio-fuels with reduced oxygen content and high combustion heat.
Obtaining bio-fuels (including gas and bio-oil) with high energy density remains a huge challenge due to their high oxygen content. Here we report a novel MoSx catalyst in-situ formed in a pilot-scale plant can effectively promote the co-hydrodeoxygenation (co-HDO) reaction of poplar wood sawdust and vacuum gas oil with H-2. Because of the sulfur vacancies on MoSx the co-HDO reaction is facilitated along with a significant accumulation of oxygen (over 50.0 wt.%) into an oil-insoluble polar-liquid, leading to a high combustion heat of similar to 47 MJ kg(-1) of the bio-fuels. Besides, the presence of MoSx also affords a lowered molecular weight of the deoxidized biofuels. Based on the underlying conversion mechanisms, the co-HDO reaction can be enhanced in the presence of MoSx catalyst by promoting oxygen transfer towards the polar-liquid during the co-HDO process.
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