Journal
APPLIED CATALYSIS B-ENVIRONMENTAL
Volume 297, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.apcatb.2021.120395
Keywords
Electrocatalytic water splitting; NiFe-LDH; Pt; Alkaline media
Funding
- National Natural Science Foundation of China [22002068, 51772162, 52072197]
- Youth Innovation and Technology Foundation of Shandong Higher Education Institutions, China [2019KJC004]
- Outstanding Youth Foundation of Shandong Province, China [ZR2019JQ14]
- Taishan Scholar Young Talent Program [tsqn201909114]
- Major Scientific and Technological Innovation Project [2019JZZY020405]
- Major Basic Research Program of Natural Science Foundation of Shandong Province [ZR2020ZD09]
- Natural Science Foundation of Shandong Province of China [ZR2019BB002, ZR2018BB031]
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Efficient and cost-effective electrocatalysts are crucial for catalyzing water electrolysis, and the NiFe-LDH-based NF-Na-Fe-Pt electrocatalyst demonstrated excellent performance and long-term durability in mediating the water-splitting process. Synergistic effects between NiFe-LDH and noble metals were found to enhance the catalytic activity for hydrogen and oxygen evolution reactions.
Developing cost-effective and highly efficient hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) electrocatalysts with small overpotentials and superior long-term stabilities is imperative for catalyzing water electrolysis. Herein, corrosion engineering is applied to synthesize NiFe-LDH incorporating noble metals on a 3D porous Ni foam at room temperature to afford the NF-Na-Fe-Pt electrocatalyst. The optimized balance adsorption of hydroxyl ions and atomic hydrogen that are manifested by the synergism between NiFe-LDH and trifle noble metals endow the nanomaterial with an excellent electrocatalytic performance and long-term durability for mediating the water-splitting process in 1 M KOH. Only 31 and 261 mV are required to drive 10 mA cm-2 of the prepared NF-Na-Fe-Pt electrocatalyst for HER and OER, respectively. DFT calculations demonstrate that Pt and NiFe-LDH synergistically accelerate the Volmer reaction and adsorption/desorption of atomic H to enhance alkaline HER. Moreover, the NF-Na-Fe-Pt electrocatalyst also exhibit remarkable catalytic activity for water splitting.
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