Anthraquinone Covalent Organic Framework Hollow Tubes as Binder Microadditives in Li-S Batteries

The exploration of new application forms of covalent organic frameworks (COFs) in Li-S batteries that can overcome drawbacks like low conductivity or high loading when typically applied as sulfur host materials (mostly approximate to 20 to approximate to 40 wt % loading in cathode) is desirable to maximize their low-density advantage to obtain lightweight, portable, or highenergy-density devices. Here, we establish that COEs could have implications as microadditives of hinders (approximate to 1 wt % in cathode), and a series of anthraquinone-COF based hollow tubes have been prepared as model microadditives. The microadditives can strengthen the basic properties of the hinder and spontaneously immobilize and catalytically convert lithium polysulfides, as proved by density functional calculations, thus showing almost doubly enhanced reversible capacity compared with that of the hare electrode.

Automated summary

The study demonstrates that COFs can act as microadditives in Li-S batteries and enhance the reversible capacity.