Journal
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
Volume 61, Issue 20, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202200180
Keywords
Aggregation-Induced Emission; Cu-I Nanoclusters; Kinetically Stable; Self-Assembly
Categories
Funding
- National Natural Science Foundation of China [91961105, 21822107, 22171164]
- Natural Science Foundation of Shandong Province [ZR2020ZD35, 2019ZD45, JQ201803, ZR2017MB061]
- Taishan Scholar Project of Shandong Province of China [tsqn201812003, ts20190908]
- Qilu Youth Scholar Funding of Shandong University
- Project for Scientific Research Innovation Team of Young Scholar in Colleges and Universities of Shandong Province [2019KJC028]
- Fok Ying Tong Education Foundation [171009]
- Key R&D Program of Shandong Province [2019GSF108158]
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This study systematically investigates the complex dynamics of a Cu-I nanocluster, Cu8a, and deduces the directed self-assembly process by monitoring the aggregation-induced emission and electron microscopy. The polymorphism and different emission properties of Cu NCs aggregates are successfully captured, and the structure-optical property relationship is established. Furthermore, the introduction of carbon dots as luminescent agents enriches the visualization fluorescence window, offering great potential for real-time optical sensing of materials.
Kinetically stable and long-lived intermediates are crucial in monitoring the progress and understanding of supramolecular self-assembly of diverse aggregated structures with collective functions. Herein, the complex dynamics of an atomically precise Cu-I nanocluster [Cu-8-((BuC6H4S)-Bu-t)(8)(PPh3)(4)] (Cu8a) is systematically investigated. Remarkably, by monitoring the aggregation-induced emission (AIE) and electron microscopy of the kinetically stable intermediates in real time, the directed sell-assembly (DSA) process of Cu8a is deduced. The polymorphism and different emission properties of Cu NCs aggregates were successfully captured, allowing the structure-optical property relationship to be established. More importantly, the utilization of a mathematical permutation and combination ideology by introducing a heterogeneous luminescent agent of a carbon dot (CD) to Cu8a aggregates enriches the visualization fluorescence window, which offers great potential in real time application for optical sensing of materials.
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