4.8 Article

Metal-Organic Frameworks with Zero and Low-Valent Metal Nodes Connected by Tetratopic Phosphine Ligands

Related references

Note: Only part of the references are listed.
Article Chemistry, Physical

Gas Adsorption Enhancement in Partially Amorphized Metal- Organic Frameworks

Saad Aldin Mohamed et al.

Summary: The study demonstrates that amorphization can improve the surface area characteristics of certain MOFs with nonaccessible regions, enhancing their competitiveness in gas uptake applications.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

Article Chemistry, Inorganic & Nuclear

Photophysical Properties of Simple Palladium(0) Complexes Bearing Triphenylphosphine Derivatives

Daichi Kakizoe et al.

Summary: This study investigated the photophysical properties of Pd(0) complexes, revealing that four-coordinated Pd(0) complexes exhibit blue-yellow emission in the solid state, while three-coordinated Pd(0) complexes display yellow-orange emission. In solution, the three-coordinated complexes show orange emission and exhibit a thermally activated delayed fluorescence mechanism. Both complexes have metal-to-ligand charge-transfer character in their emitting states, but the emission of the tris complex is significantly influenced by a metal-centered d -> p transition.

INORGANIC CHEMISTRY (2021)

Article Chemistry, Multidisciplinary

Zero-valent metals in metal-organic frameworks: fac-M(CO)3(pyrazine)3/2

Laura Voigt et al.

Summary: This study reports the synthesis of pyrazine-pillared metal-organic frameworks (MOFs) through ligand substitution of Group 6 metal hexacarbonyls. The obtained frameworks have hexagonal pore channels with CO-plastered porewalls, representing the first crystallographically characterized examples of Cr(0), Mo(0), and W(0)-based MOFs. The study suggests exploring homoleptic metal carbonyls as starting materials to generate polymeric materials with low-valent metal nodes.

CHEMICAL COMMUNICATIONS (2021)

Review Chemistry, Multidisciplinary

Microporous Metal-Organic Framework Materials for Gas Separation

Rui-Biao Lin et al.

Review Chemistry, Multidisciplinary

Metal-Organic Framework-Based Catalysts with Single Metal Sites

Yong-Sheng Wei et al.

CHEMICAL REVIEWS (2020)

Article Chemistry, Multidisciplinary

Mercury 4.0: from visualization to analysis, design and prediction

Clare F. Macrae et al.

JOURNAL OF APPLIED CRYSTALLOGRAPHY (2020)

Article Chemistry, Multidisciplinary

Standard Practices of Reticular Chemistry

Cornelius Gropp et al.

ACS CENTRAL SCIENCE (2020)

Article Chemistry, Multidisciplinary

Modulated self-assembly of metal-organic frameworks

Ross S. Forgan

CHEMICAL SCIENCE (2020)

Article Chemistry, Multidisciplinary

Isolating reactive metal-based species in Metal-Organic Frameworks - viable strategies and opportunities

Rosemary J. Young et al.

CHEMICAL SCIENCE (2020)

Article Nanoscience & Nanotechnology

Optoelectronic Properties of High Triplet σ-π-Conjugated Poly[(biphenyl group IV-A atom (C, Si, Ge, Sn)] Backbones

Miao-Ken Hung et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

Article Chemistry, Physical

Metal-Organic Frameworks in Solid-Gas Phase Catalysis

Cheng Wang et al.

ACS CATALYSIS (2019)

Review Chemistry, Multidisciplinary

Improving MOF stability: approaches and applications

Meili Ding et al.

CHEMICAL SCIENCE (2019)

Article Chemistry, Multidisciplinary

A Metal-Organic Framework with Cooperative Phosphines That Permit Post-Synthetic Installation of Open Metal Sites

Samuel G. Dunning et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Review Chemistry, Multidisciplinary

Site Isolation in Metal-Organic Frameworks Enables Novel Transition Metal Catalysis

Tasha Drake et al.

ACCOUNTS OF CHEMICAL RESEARCH (2018)

Article Chemistry, Inorganic & Nuclear

Tetraphosphines with tetra(biphenyl) silane and - stannane cores as rigid scaffold linkers for immobilized catalysts

Joseph H. Baker et al.

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2017)

Article Chemistry, Multidisciplinary

Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3-Dimensional Ni(0) Framework with m-Terphenyl Diisocyanides

Douglas W. Agnew et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Inorganic & Nuclear

Tetraphenylethylene-based phosphine: tuneable emission and carbon dioxide fixation

Jianyong Zhang et al.

DALTON TRANSACTIONS (2014)

Review Multidisciplinary Sciences

The Chemistry and Applications of Metal-Organic Frameworks

Hiroyasu Furukawa et al.

SCIENCE (2013)

Article Chemistry, Multidisciplinary

Supramolecular Tetrahedra of Phosphines and Coinage Metals

Sang Ho Lim et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

Article Chemistry, Multidisciplinary

Easily immobilized di- and tetraphosphine linkers:: Rigid scaffolds that prevent interactions of metal complexes with oxide supports

Yuan Yang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)