Journal
AMERICAN MINERALOGIST
Volume 106, Issue 10, Pages 1559-1573Publisher
MINERALOGICAL SOC AMER
DOI: 10.2138/am-2021-7637
Keywords
Melt inclusion; fluid inclusion; Taishanmiao batholith; liquidus deficit; volatile-saturated melt; Rhyolite-MELTS; pegmatite; Experimental Halogens in Honor of James Webster
Categories
Funding
- National Nonprofit Institute Research Grant of the Chinese Academy of Geological Sciences [YYWF201711]
- Chinese Scholarship Council
- National Science Foundation [EAR-1624589]
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The Taishanmiao granitic batholith in Henan Province, China contains numerous small bodies of simple quartz and alkali feldspar pegmatites. Analysis and modeling suggest that the pegmatites formed through continuous fractional crystallization of the granitic magma, with a mineral assemblage similar to that of the pegmatites and residual melt composition similar to homogenized melt inclusions. The closed system, isochoric model proposes that the pegmatites began forming after most of the granitic melt had crystallized, with fluctuating pressure conditions leading to the formation of pegmatitic textures.
The Taishanmiao granitic batholith, located in the Eastern Qinling Orogen in Henan Province, China, contains numer-ous small (mostly tens of centimeters in maximum dimension) bodies exhibiting textures and mineralogy characteristics of simple quartz and alkali feldspar pegmatites. Analysis of melt inclusions (MI) and fluid inclusions (FI) in pegmatitic quartz, combined with Rhyolite-MELTS modeling of the crystallization of the granite, have been applied to develop a conceptual model of the physical and geochemical processes associated with the formation of the pegmatites. These results allow us to consider the formation of the Taishanmiao pegmatites within the context of varios models that have been proposed for pegmatite formation. Field observations and geochemical data indicate that the pegmatites represent the latest stage in the crystallization of the Taishanmiao granite and occupy <4 vol% of the syenogranite phase of the batholith. Results of Rhyolite-MELTS modeling suggest that the pegmatite-forming melts can be produced through continuous fractional crystallization of the Taishanmiao granitic magma, consistent with the designation of the pegmatites as a miarolitic class, segregation-type pegmatites rather than the more common intrusive-type of pegmatite. The mineral assemblage predicted by Rhyolite-MELTS after-96% of the original granite-forming melt had crystallized consists of-51 vol% alkali feldspar, 34 vol% quartz, 14 vol% plagioclase, 0.1 vol% biotite, and 1 vol% magnetite, similar to the alkali feldspar + quartz dominated mineralogy of the pegmatites. Moreover, the modeled residual melt composition following crystallization of-96% of the original melt is similar to the composition of homogenized MI in quartz within the pegmatite. Rhyolite-MELTS predicts that the granite-forming melt remained volatile-undersaturated during crystallization of the batholith and contained-6.3 wt% H2O and-500 ppm CO2 after-96% crystallization when the pegmatites began to develop. The Rhyolite-MELTS prediction that the melt was volatile-undersaturated at the time the pegmatites began to form, but became volatile-saturated during the early stages of pegmatite formation, is consistent with the presence of some inclusion assemblages consisting of only MI, while others contain co-existing MI and FI. The relationship between halogen (F and Cl) and Na abundances in MI is also consistent with the interpretation that the very earliest stages of pegmatite formation occurred in the presence of a volatile-undersaturated melt and that the melt became volatile saturated as crystallization progressed. We propose a closed system, isochoric model for the formation of the pegmatites. Accordingly, the Taishanmiao granite crystallized isobarically at-3.3 kbar, and the pegmatites began to form at-734 degrees C and -3.3 kbar, after-96% of the original granitic melt had crystallized. During the final stages of crystallization of the granite, small pockets of the remaining residual melt became isolated within the enclosing granite and evolved as constant mass (closed), constant volume (isochoric) systems, similar to the manner in which volatile-rich melt inclusions in igneous phenocrysts evolve during post-entrapment crystallization under isochoric conditions. As a result of the negative volume change associated with crystallization, pressure in the pegmatite initially decreases as crystals form, and this leads to volatile exsolution from the melt phase. The changing PTX conditions produce a pressure-induced liquidus deficit that is analogous to liquidus undercooling and results in crystal growth as required to return the system to equilibrium PTX conditions. Ow-ing to the complex closed system, isochoric PVTX evolution of the melt-crystal-volatile system, the pressure does not decrease rapidly or monotonically during pegmatite formation but, rather, gradually fluctuates such that at some stages in the evolution of the pegmatite the pressure is decreasing while at other times the pressure increases as the system cools to maintain mass and volume balance. This behavior, in turn, leads to alternating episodes of precipitation and dis -solution that serve to coarsen (ripen) the crystals to produce the pegmatitic texture. The evolution of the pegmatitic melt described here is analogous to that which has been well-documented to occur in volatile-rich MI that undergo closed system, isochoric, post-entrapment crystallization.
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