Journal
ADVANCES IN WATER RESOURCES
Volume 160, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.advwatres.2021.104102
Keywords
Per- and polyfluoroalkyl substances (PFAS); Leaching; Interfacial adsorption; Analytical solution; Rate-limited adsorption; Unsaturated zone
Categories
Funding
- Environmental Security Technol-ogy Certification Program, United States [ER21-5041]
- Na-tional Science Foundation, United States [2023351]
- Superfund Research Program of the NIEHS [P42 ES4940]
- Directorate For Geosciences
- Division Of Earth Sciences [2023351] Funding Source: National Science Foundation
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This study developed a simplified analytical model for quantifying long-term PFAS leaching in the vadose zone and validated its accuracy and efficiency.
A growing body of site investigations have demonstrated that vadose zones serve as significant long-term sources of PFAS to groundwater. Quantifying PFAS leaching in the vadose zone and mass discharge to groundwater is therefore critical for characterizing, managing, and mitigating long-term contamination risks. Mathematical models representing the PFAS-specific transport and retention processes, including surfactant-induced flow, and rate-limited, nonlinear adsorption at solid-water and air-water interfaces, have been recently developed. While these advanced models provide fundamental insights into the primary processes controlling the long-term retention of PFAS, they are less suitable for screening-type applications due to significant computational cost and the requirement for detailed input parameters. To address this knowledge gap, we develop a simplified model by assuming steady-state infiltration and linear solid-phase and air-water interfacial adsorption; a two-domain model is used to represent kinetic solid-phase adsorption. We derive novel analytical solutions for the simplified model allowing for arbitrary initial conditions. The newly derived analytical solutions are then validated by application to miscible-displacement experiments under a wide range of conditions and by comparisons to a state-of-the-art comprehensive model under both experimental and field conditions applicable to PFAS-contamination sites. Overall, the simplified analytical model provides an efficient and accurate screening-type tool for quantifying long-term PFAS leaching in the vadose zone.
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