Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 364, Issue 1, Pages 193-199Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202100921
Keywords
Cobalt; Dioxygenation; Styrene; N-Hydroxyphthalimide; Oxygen
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Funding
- Scientific Research Project of Hubei Education Department [D20201405, T2020023]
- Jingmen Science and Technology Project [ZDCX2017004, 2020ZDYF002]
- open project of Hubei Provincial Key Laboratory of Green Materials for Light Industry [202007 A04]
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Cobalt-catalyzed selective dioxygenation of styrenes with NHPI using molecular oxygen as the terminal oxidant allows for selective formation of alcohol and ketone products from identical substrates. The reaction is applicable to a broad range of styrenes and exhibits good functional group tolerance, providing a method for preparation of 1,2-diol or alpha-hydroxyketone derivatives.
A cobalt-catalyzed selective dioxygenation of styrenes with N-hydroxyphthalimide (NHPI) was developed using molecular oxygen as the terminal oxidant. Alcohol and ketone products can be selectively formed from identical substrates by catalyst control. The reaction was applicable to a broad range of styrenes and exhibited good functional group tolerance. It provided a method for preparation of 1,2-diol or alpha-hydroxyketone derivatives.
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