4.8 Review

Molecular Cleavage of Metal-Organic Frameworks and Application to Energy Storage and Conversion

Related references

Note: Only part of the references are listed.
Review Chemistry, Multidisciplinary

Electrocatalytic Refinery for Sustainable Production of Fuels and Chemicals

Cheng Tang et al.

Summary: The emerging electrocatalytic refinery (e-refinery) is a more sustainable and environmentally friendly strategy for converting renewable feedstocks and energy sources into transportable fuels and chemicals. Challenges remain in understanding mechanistic aspects and materials design for complex reactions in e-refinery processes.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Review Chemistry, Multidisciplinary

Metal-Organic Frameworks Derived Functional Materials for Electrochemical Energy Storage and Conversion: A Mini Review

Xue Feng Lu et al.

Summary: Metal-organic frameworks (MOFs) have been recognized as versatile precursors or templates for preparing high-performance electrodes or catalysts in electrochemical energy storage and conversion (EESC), due to their high surface area, tunable pore sizes, and diverse chemical compositions and physical structures. Research focuses on the composition/structure/performance relationship and practical applications in various EESC systems, providing insights into the future development of MOF-derived functional materials.

NANO LETTERS (2021)

Review Chemistry, Physical

Modulating Metal-Organic Frameworks as Advanced Oxygen Electrocatalysts

Zhaoqiang Li et al.

Summary: Oxygen-related electrocatalysis plays a central role in green-energy technologies. Metal-organic frameworks (MOFs) have drawn extensive attention as nonprecious oxygen electrocatalysts due to their tunable compositions. Various strategies have been developed to fabricate MOF-based electrocatalysts and regulate their active sites.

ADVANCED ENERGY MATERIALS (2021)

Article Chemistry, Multidisciplinary

Molecular Surgery at Microporous MOF for Mesopore Generation and Renovation

Mohamed K. Albolkany et al.

Summary: Hierarchically porous MOFs (HP-MOFs) exhibit advantageous synergism of micro- and mesopore structures, but face challenges in synthetic control at a molecular scale. This study presents a novel approach for reversible and controllable mesopore generation and renovation in microporous MOFs like HKUST-1, achieved through gas-phase etching to create uniform mesopores without altering crystal size or morphology. The generated mesopores can be further modified using MOF precursor solutions, demonstrating a powerful protocol for precisely tailoring and tuning the properties of MOF materials at a molecular scale.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

Molecular Scalpel to Chemically Cleave Metal-Organic Frameworks for Induced Phase Transition

Xianlong Zhou et al.

Summary: This study introduces a top-down strategy to trigger phase transition in MOFs via structural cleavage using a novel molecular scalpel, leading to significant changes in structure diversity and catalytic activity.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Article Chemistry, Multidisciplinary

Engineering Two-Dimensional Metal-Organic Framework on Molecular Basis for Fast Li+ Conduction

Jianming Yu et al.

Summary: This study demonstrates the feasibility of engineering fast Li+ conduction within MOF on molecule conception. By developing a novel Cu(BDC)-scaffold-reinforced CPE, high Li+ conductivity and mechanical strength are achieved. This molecule-basis Li+ conduction strategy provides new ideas for designing advanced CPEs.

NANO LETTERS (2021)

Article Nanoscience & Nanotechnology

Permselective metal-organic framework gel membrane enables long-life cycling of rechargeable organic batteries

Songyan Bai et al.

Summary: The use of MOF gel separators in organic batteries can effectively address electrode dissolution and shuttle effect issues, improving cycle stability and capacity retention. This technology has great potential for various applications, as the pore size can be tailored to specific organic electrode materials.

NATURE NANOTECHNOLOGY (2021)

Article Chemistry, Multidisciplinary

Electron-State Confinement of Polysulfides for Highly Stable Sodium-Sulfur Batteries

Chao Ye et al.

ADVANCED MATERIALS (2020)

Review Chemistry, Multidisciplinary

Metal-Organic Frameworks Based Electrocatalysts for the Oxygen Reduction Reaction

Xue Feng Lu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Engineering a Highly Defective Stable UiO-66 with Tunable Lewis-Bronsted Acidity: The Role of the Hemilabile Linker

Xiao Feng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Chemistry, Multidisciplinary

Multistep Engineering of Synergistic Catalysts in a Metal-Organic Framework for Tandem C-O Bond Cleavage

Yang Song et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Chemistry, Multidisciplinary

Constructing a Super-Saturated Electrolyte Front Surface for Stable Rechargeable Aqueous Zinc Batteries

Huijun Yang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Rapid Generation of Hierarchically Porous Metal-Organic Frameworks through Laser Photolysis

Kun-Yu Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Metal-Organic Framework-Derived Carbon Nanorods Encapsulating Bismuth Oxides for Rapid and Selective CO2 Electroreduction to Formate

Peilin Deng et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Article Chemistry, Multidisciplinary

Hierarchy in Metal-Organic Frameworks

Liang Feng et al.

ACS CENTRAL SCIENCE (2020)

Review Multidisciplinary Sciences

Roadmap for advanced aqueous batteries: From design of materials to applications

Dongliang Chao et al.

SCIENCE ADVANCES (2020)

Article Chemistry, Multidisciplinary

Hydrophobic Organic-Electrolyte-Protected Zinc Anodes for Aqueous Zinc Batteries

Longsheng Cao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Review Chemistry, Multidisciplinary

Electronic Structure Modeling of Metal-Organic Frameworks

Jenna L. Mancuso et al.

CHEMICAL REVIEWS (2020)

Review Chemistry, Multidisciplinary

Destruction of Metal-Organic Frameworks: Positive and Negative Aspects of Stability and Lability

Liang Feng et al.

CHEMICAL REVIEWS (2020)

Review Chemistry, Inorganic & Nuclear

Exchange reactions in metal-organic frameworks: New advances

Ming-Ming Xu et al.

COORDINATION CHEMISTRY REVIEWS (2020)

Review Chemistry, Multidisciplinary

Strategies for Pore Engineering in Zirconium Metal-Organic Frameworks

Liang Feng et al.

Article Chemistry, Multidisciplinary

Intermediate Binding Control Using Metal-Organic Frameworks Enhances Electrochemical CO2 Reduction

Dae-Hyun Nam et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Review Chemistry, Multidisciplinary

A historical overview of the activation and porosity of metal-organic frameworks

Xuan Zhang et al.

CHEMICAL SOCIETY REVIEWS (2020)

Review Chemistry, Multidisciplinary

Synthesis of micro/nanoscaled metal-organic frameworks and their direct electrochemical applications

Xiao Xiao et al.

CHEMICAL SOCIETY REVIEWS (2020)

Review Materials Science, Multidisciplinary

Rational Design of Metal-Organic Frameworks towards Efficient Electrocatalysis

Shuo Dou et al.

ACS MATERIALS LETTERS (2020)

Review Chemistry, Multidisciplinary

Towards practical lithium-metal anodes

Xin Zhang et al.

CHEMICAL SOCIETY REVIEWS (2020)

Review Chemistry, Multidisciplinary

Coordinatively unsaturated metal sites (open metal sites) in metal-organic frameworks: design and applications

Ulku Kokcam-Demir et al.

CHEMICAL SOCIETY REVIEWS (2020)

Review Chemistry, Multidisciplinary

MOF-derived electrocatalysts for oxygen reduction, oxygen evolution and hydrogen evolution reactions

Hao-Fan Wang et al.

CHEMICAL SOCIETY REVIEWS (2020)

Article Chemistry, Multidisciplinary

Boosting Electrochemical CO2 Reduction on Metal-Organic Frameworks via Ligand Doping

Shuo Dou et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

An Electrolytic Zn-MnO2 Battery for High-Voltage and Scalable Energy Storage

Dongliang Chao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

Coordinative Reduction of Metal Nodes Enhances the Hydrolytic Stability of a Paddlewheel Metal-Organic Framework

Dahae Song et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Review Chemistry, Multidisciplinary

Understanding the Roadmap for Electrochemical Reduction of CO2 to Multi-Carbon Oxygenates and Hydrocarbons on Copper-Based Catalysts

Yao Zheng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Multidisciplinary

Generation of Hierarchical Porosity in Metal-Organic Frameworks by the Modulation of Cation Valence

Shi-Chao Qi et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Multidisciplinary

Cleaving Carboxyls: Understanding Thermally Triggered Hierarchical Pores in the Metal-Organic Framework MIL-121

Shoushun Chen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Multidisciplinary

Lithium Thiophosphate Functionalized Zirconium MOFs for Li-S Batteries with Enhanced Rate Capabilities

Avery E. Baumann et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Multidisciplinary Sciences

Missing-linker metal-organic frameworks for oxygen evolution reaction

Ziqian Xue et al.

NATURE COMMUNICATIONS (2019)

Review Materials Science, Multidisciplinary

Metal-organic frameworks: Structures and functional applications

Long Jiao et al.

MATERIALS TODAY (2019)

Article Chemistry, Multidisciplinary

Directional Engraving within Single Crystalline Metal-Organic Framework Particles via Oxidative Linker Cleaving

Lianshun Luo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Multidisciplinary

A versatile single-ion electrolyte with a Grotthuss-like Li conduction mechanism for dendrite-free Li metal batteries

Shouyi Yuan et al.

ENERGY & ENVIRONMENTAL SCIENCE (2019)

Review Chemistry, Physical

Recent Advances for MOF-Derived Carbon-Supported Single-Atom Catalysts

Aijuan Han et al.

SMALL METHODS (2019)

Article Chemistry, Multidisciplinary

The potential of electrolyte filled MOF membranes as ionic sieves in rechargeable batteries

Yibo He et al.

ENERGY & ENVIRONMENTAL SCIENCE (2019)

Review Chemistry, Multidisciplinary

Understanding Conversion-Type Electrodes for Lithium Rechargeable Batteries

Seung-Ho Yu et al.

ACCOUNTS OF CHEMICAL RESEARCH (2018)

Article Nanoscience & Nanotechnology

Photothermal Activation of Metal-Organic Frameworks Using a UV-Vis Light Source

Jordi Espin et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

Article Chemistry, Multidisciplinary

Creating Lithium-Ion Electrolytes with Biomimetic Ionic Channels in Metal-Organic Frameworks

Li Shen et al.

ADVANCED MATERIALS (2018)

Review Chemistry, Multidisciplinary

Defective Metal-Organic Frameworks

Stefano Dissegna et al.

ADVANCED MATERIALS (2018)

Article Chemistry, Multidisciplinary

Electrochemical Exfoliation of Pillared-Layer Metal-Organic Framework to Boost the Oxygen Evolution Reaction

Jin Huang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Chemistry, Multidisciplinary

Creating Hierarchical Pores by Controlled Linker Thermolysis in Multivariate Metal-Organic Frameworks

Liang Feng et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Multidisciplinary Sciences

Ordered macro-microporous metal-organic framework single crystals

Kui Shen et al.

SCIENCE (2018)

Article Chemistry, Multidisciplinary

Metal-Organic Frameworks Mediate Cu Coordination for Selective CO2 Electroreduction

Dae-Hyun Nam et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Article Multidisciplinary Sciences

Metal-organic framework patterns and membranes with heterogeneous pores for flow-assisted switchable separations

Guan-Young Jeong et al.

NATURE COMMUNICATIONS (2018)

Article Chemistry, Multidisciplinary

Postsynthetic Selective Ligand Cleavage by Solid-Gas Phase Ozonolysis Fuses Micropores into Mesopores in Metal-Organic Frameworks

Vincent Guillerm et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

Review Multidisciplinary Sciences

Secondary building units as the turning point in the development of the reticular chemistry of MOFs

Markus J. Kalmutzki et al.

SCIENCE ADVANCES (2018)

Article Chemistry, Multidisciplinary

A Modulator-Induced Defect-Formation Strategy to Hierarchically Porous Metal-Organic Frameworks with High Stability

Guorui Cai et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Article Chemistry, Multidisciplinary

Single-Ion Li+, Na+, and Mg2+ Solid Electrolytes Supported by a Mesoporous Anionic Cu-Azolate Metal-Organic Framework

Sarah S. Park et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

Metal-Organic Nanosheets Formed via Defect-Mediated Transformation of a Hafnium Metal-Organic Framework

Matthew J. Cliffe et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

Controlled Intercalation and Chemical Exfoliation of Layered Metal-Organic Frameworks Using a Chemically Labile Intercalating Agent

Yanjun Ding et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Multidisciplinary Sciences

Janus dendrimersomes coassembled from fluorinated, hydrogenated, and hybrid Janus dendrimers as models for cell fusion and fission

Qi Xiao et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2017)

Article Multidisciplinary Sciences

Construction of hierarchically porous metal-organic frameworks through linker labilization

Shuai Yuan et al.

NATURE COMMUNICATIONS (2017)

Review Chemistry, Physical

Design Strategies toward Advanced MOF-Derived Electrocatalysts for Energy-Conversion Reactions

Jinlong Liu et al.

ADVANCED ENERGY MATERIALS (2017)

Article Chemistry, Multidisciplinary

Multi-shelled Hollow Metal-Organic Frameworks

Wenxian Liu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Article Chemistry, Physical

Missing Linkers: An Alternative Pathway to UiO-66 Electronic Structure Engineering

Arthur De Vos et al.

CHEMISTRY OF MATERIALS (2017)

Review Chemistry, Multidisciplinary

Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide

Dong Dong Zhu et al.

ADVANCED MATERIALS (2016)

Article Energy & Fuels

Metal-organic framework-based separator for lithium-sulfur batteries

Songyan Bai et al.

NATURE ENERGY (2016)

Article Chemistry, Multidisciplinary

Post-Synthetic Anisotropic Wet-Chemical Etching of Colloidal Sodalite ZIF Crystals

Civan Avci et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Multidisciplinary

Hydrolytic Transformation of Microporous Metal-Organic Frameworks to Hierarchical Micro- and Mesoporous MOFs

Yonghwi Kim et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Multidisciplinary

Hierarchical Pore Development by Plasma Etching of Zr-Based Metal-Organic Frameworks

Jared B. DeCoste et al.

CHEMISTRY-A EUROPEAN JOURNAL (2015)

Article Chemistry, Multidisciplinary

A Chemical Route to Activation of Open Metal Sites in the Copper-Based Metal-Organic Framework Materials HKUST-1 and Cu-MOF-2

Hong Ki Kim et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Article Chemistry, Multidisciplinary

Exploiting chemically selective weakness in solids as a route to new porous materials

Russell E. Morris et al.

Nature Chemistry (2015)

Article Multidisciplinary Sciences

An in situ self-assembly template strategy for the preparation of hierarchical-pore metal-organic frameworks

Hongliang Huang et al.

NATURE COMMUNICATIONS (2015)

Review Chemistry, Multidisciplinary

Solvent-Assisted Linker Exchange: An Alternative to the De Novo Synthesis of Unattainable Metal-Organic Frameworks

Olga Karagiaridi et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

Review Chemistry, Multidisciplinary

Post-synthetic metalation of metal-organic frameworks

Jack D. Evans et al.

CHEMICAL SOCIETY REVIEWS (2014)

Article Chemistry, Multidisciplinary

Rational design of a metal-organic framework host for sulfur storage in fast, long-cycle Li-S batteries

Junwen Zhou et al.

ENERGY & ENVIRONMENTAL SCIENCE (2014)

Article Chemistry, Multidisciplinary

Ordered Vacancies and Their Chemistry in Metal Organic Frameworks

Binbin Tu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

Article Multidisciplinary Sciences

Correlated defect nanoregions in a metal-organic framework

Matthew J. Cliffe et al.

NATURE COMMUNICATIONS (2014)

Article Chemistry, Multidisciplinary

Perfluoroalkane Functionalization of NU-1000 via Solvent-Assisted Ligand Incorporation: Synthesis and CO2 Adsorption Studies

Pravas Deria et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Article Chemistry, Multidisciplinary

Synthesis Modulation as a Tool To Increase the Catalytic Activity of Metal-Organic Frameworks: The Unique Case of UiO-66(Zr)

Frederik Vermoortele et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Article Chemistry, Multidisciplinary

High H-2 adsorption in a microporous metal-organic framework with open metal sites

BL Chen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2005)

Article Chemistry, Applied

Improved synthesis, thermal stability and catalytic properties of the metal-organic framework compound CU3(BTC)2

K Schlichte et al.

MICROPOROUS AND MESOPOROUS MATERIALS (2004)