4.8 Article

Nanostructure Control in 3D Printed Materials

Journal

ADVANCED MATERIALS
Volume 34, Issue 4, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.202107643

Keywords

3D printing; in situ polymerization-induced microphase separation; multi-materials; nanostructured materials; RAFT polymerization

Funding

  1. Australian Research Council
  2. UNSW Australia [DP210100094]

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A novel approach for fabricating materials with controlled nanoscale morphologies using Digital Light Processing 3D printing technique has been demonstrated. This method utilizes reversible deactivation radical polymerization to control the microphase separation of printing resins, resulting in materials with enhanced mechanical properties.
Currently, there are no straightforward methods to 3D print materials with nanoscale control over morphological and functional properties. Here, a novel approach for the fabrication of materials with controlled nanoscale morphologies using a rapid and commercially available Digital Light Processing 3D printing technique is demonstrated. This process exploits reversible deactivation radical polymerization to control the in-situ-polymerization-induced microphase separation of 3D printing resins, which provides materials with complex architectures controllable from the macro- to nanoscale, resulting in the preparation of materials with enhanced mechanical properties. This method does not require specialized equipment or process conditions and thus represents an important development in the production of advanced materials via additive manufacturing.

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