Challenges and Strategies of Low-Cost Aluminum Anodes for High-Performance Al-Based Batteries

The ever-growing market of electric vehicles and the upcoming grid-scale storage systems have stimulated the fast growth of renewable energy storage technologies. Aluminum-based batteries are considered one of the most promising alternatives to complement or possibly replace the current lithium-ion batteries owing to their high specific capacity, good safety, low cost, light weight, and abundant reserves of Al. However, the anode problems in primary and secondary Al batteries, such as, self-corrosion, passive film, and volume expansion, severely limit the batteries' practical performance, thus hindering their commercialization. Herein, an overview of the currently emerged Al-based batteries is provided, that primarily focus on the recent research progress for Al anodes in both primary and rechargeable systems. The anode reaction mechanisms and problems in various Al-based batteries are discussed, and various strategies to overcome the challenges of Al anodes, including surface oxidation, self-corrosion, volume expansion, and dendrite growth, are systematically summarized. Finally, future research perspectives toward advanced Al batteries with higher performance and better safety are presented.

Automated summary

The market growth of electric vehicles and grid-scale storage systems has driven the development of renewable energy storage technologies, with aluminum-based batteries emerging as a promising alternative to lithium-ion batteries. Despite their potential, challenges like self-corrosion and volume expansion in aluminum anodes hinder their commercialization. This article provides an overview of various aluminum-based batteries and strategies to address the anode-related issues for future development of advanced aluminum batteries.