4.8 Article

Molecular Engineering of 2D Nanomaterial Field-Effect Transistor Sensors: Fundamentals and Translation across the Innovation Spectrum

Journal

ADVANCED MATERIALS
Volume 34, Issue 3, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.202106975

Keywords

2D nanomaterials; field-effect transistors; field testbed; real-time water sensors; technology translation

Funding

  1. US National Science Foundation (NSF) Scalable Nanomanufacturing Program [NSF CMMI-1727846, CMMI-2039268]
  2. NSF Future Manufacturing Program [NSF CMMI-2037026]
  3. NSF Nanosystems Engineering Research Center on Nanotechnology-Enabled Water Treatment [EEC-1449500]
  4. Laboratory Directed Research and Development (LDRD) program from Argonne National Laboratory
  5. Office of Science, of the U.S. Department of Energy [DE-AC02-06CH11357]

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2D layered nanomaterials have gained attention for their unique properties, with potential for environmental sensors capable of detecting water contaminants. Challenges and opportunities exist in designing and fabricating high-performance sensors, as illustrated through case studies on graphene-based water sensors and large-scale sensor networks for water-quality monitoring. The potential of 2D nanomaterial FET sensors in enabling intelligent water systems and addressing precarious water supplies globally is significant.
Over the last decade, 2D layered nanomaterials have attracted significant attention across the scientific community due to their rich and exotic properties. Various nanoelectronic devices based on these 2D nanomaterials have been explored and demonstrated, including those for environmental applications. Here, the fundamental attributes of 2D layered nanomaterials for field-effect transistor (FET) sensors and tunneling FET (TFET) sensors, which provide versatile detection of water contaminants such as heavy-metal ions, bacteria, nutrients, and organic pollutants, are discussed. The major challenges and opportunities are also outlined for designing and fabricating 2D nanomaterial FET/TFET sensors with superior performance. Translation of these FET/TFET sensors from fundamental research to applied technology is illustrated through a case study on graphene-based real-time FET water sensors. A second case study centers on large-scale sensor networks for water-quality monitoring to enable intelligent drinking water and river-water systems. Overall, 2D nanomaterial FET sensors have significant potential for enabling a human-centered intelligent water system that can likely be applied to other precarious water supplies around the globe.

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