Recent Progress on Self-Healable Conducting Polymers

Materials able to regenerate after damage have been the object of investigation since the ancient times. For instance, self-healing concretes, able to resist earthquakes, aging, weather, and seawater have been known since the times of ancient Rome and are still the object of research. During the last decade, there has been an increasing interest in self-healing electronic materials, for applications in electronic skin (E-skin) for health monitoring, wearable and stretchable sensors, actuators, transistors, energy harvesting, and storage devices. Self-healing materials based on conducting polymers are particularly attractive due to their tunable high conductivity, good stability, intrinsic flexibility, excellent processability and biocompatibility. Here recent developments are reviewed in the field of self-healing electronic materials based on conducting polymers, such as poly 3,4-ethylenedioxythiophene (PEDOT), polypyrrole (PPy), and polyaniline (PANI). The different types of healing, the strategies adopted to optimize electrical and mechanical properties, and the various possible healing mechanisms are introduced. Finally, the main challenges and perspectives in the field are discussed.

Automated summary

Materials that can regenerate themselves after being damaged have been studied for a long time. Recently, there has been a growing interest in self-healing electronic materials for various applications. Conducting polymers, such as PEDOT, PPy, and PANI, are particularly attractive due to their high conductivity, stability, flexibility, processability, and biocompatibility. This review article discusses recent developments in the field, including different types of healing, strategies to optimize electrical and mechanical properties, and future challenges and perspectives.