4.8 Review

Exciton-Polaritons and Their Bose-Einstein Condensates in Organic Semiconductor Microcavities

Journal

ADVANCED MATERIALS
Volume 34, Issue 4, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.202106095

Keywords

Bose-Einstein condensation; exciton-polaritons; light-matter interactions; organic semiconductor; polariton condensation; strong coupling

Funding

  1. Ministry of Science and Technology of China [2017YFA0204502, 2018YFA0704802]
  2. National Natural Science Foundation of China [21922307, 22090023, 21773265, 21790364]
  3. Beijing Natural Science Foundation [JQ20006]

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Exciton-polaritons are bosonic quasiparticles formed by strong exciton-photon coupling in semiconductor microcavities, exhibiting strong nonlinear interactions and retaining most characteristics of photons. Organic semiconductors, known for their stability and photophysical properties, have become a promising platform for these studies. Recent advances in exciton-polaritons and their Bose-Einstein condensates in organic semiconductor microcavities have been summarized, with future research directions focusing on addressing remaining questions and exploring new applications.
Exciton-polaritons are half-light, half-matter bosonic quasiparticles formed by strong exciton-photon coupling in semiconductor microcavities. These hybrid particles possess the strong nonlinear interactions of excitons and keep most of the characteristics of the underlying photons. As bosons, above a threshold density they can undergo Bose-Einstein condensation to a polariton condensate phase and exhibit a rich variety of exotic macroscopic quantum phenomena in solids. Recently, organic semiconductors have been considered as a promising material platform for these studies due to their room-temperature stability, good processability, and abundant photophysics and photochemistry. Herein, recent advances of exciton-polaritons and their Bose-Einstein condensates in organic semiconductor microcavities are summarized. First, the basic physics is introduced, and then their emerging applications are highlighted. The remaining questions are also discussed and a personal viewpoint about the potential directions for future research is given.

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