4.8 Article

Molecular Doping Efficiency in Organic Semiconductors: Fundamental Principle and Promotion Strategy

Journal

ADVANCED FUNCTIONAL MATERIALS
Volume 32, Issue 12, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adfm.202111351

Keywords

doping efficiency; ground-state charge transfer; molecular doping; organic semiconductors; statistical models

Funding

  1. National Natural Science Foundation of China [21975198, 51803162]
  2. Open Fund of the State Key Laboratory of Luminescent Materials and Devices (South China University of Technology) [2021-skllmd-12]

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Molecular doping is a fascinating technique to modulate the electrical property of organic solids by importing additional charges, and the central challenge currently lies in improving the efficiency of the doping process. Future directions to achieve this goal are further research and improvements in efficiency.
Molecular doping, a fascinating technique to modulate the electrical property of organic solids by importing additional charges, has been one of the focal points of active research over the last three decades. Due to the potential applications in clean energy and artificial intelligence, molecular doping is experiencing a second golden stage by virtue of its compatibility with solution-processed organic functional devices. The central challenge at present promoting the doping efficiency. This perspective starts with revisiting the basic concepts in doping process and discusses the recent progress in efficiency improvements. Based on the journey of molecular doping, it is concluded that molecular doping can be as efficient as atomic doping is in inorganic semiconductors; future directions to achieve this goal are shared.

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