4.8 Article

Visualization of Polymer Dynamics in Cellulose Nanocrystal Matrices Using Fluorescence Lifetime Measurements

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 14, Issue 8, Pages 10793-10804

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.1c21906

Keywords

cellulose nanocrystals; polymer dynamics; interfaces; thermoresponsive polymer; fluorescence lifetime imaging microscopy (FLIM)

Funding

  1. Graduate Fellowships for STEM Diversity
  2. AFOSR
  3. P3Nano

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This study investigates the effect of polymer dynamics in CNC nanocomposites by attaching a water-sensitive dye to the polymer and using fluorescence lifetime imaging microscopy. The research shows that polymer chains with high mobility improve the strain and toughness of CNC films.
Polymer nanocomposites containing self-assembled cellulose nanocrystals (CNCs) are ideal for advanced applications requiring both strength and toughness as the helicoidal structure of the CNCs deflects crack propagation and the polymer matrix dissipates impact energy. However, any adsorbed water layer surrounding the CNCs may compromise the interfacial adhesion between the polymer matrix and the CNCs, thus impacting stress transfer at that interface. Therefore, it is critical to study the role of water at the interface in connecting the polymer dynamics and the resulting mechanical performance of the nanocomposite. Here, we explore the effect of polymer confinement and water content on polymer dynamics in CNC nanocomposites by covalently attaching a fluorogenic water-sensitive dye to poly(diethylene glycol methyl ether methacrylate) (PMEO(2)MA), to provide insights into the observed mechanical performance. Utilizing fluorescence lifetime imaging microscopy (FLIM), the lifetime of dye fluorescence decay was measured to probe the polymer chain dynamics of PMEO(2)MA in CNC nanocomposite films. The PMEO(2)MA chains experienced distinct regions of differing dynamics within Bouligand structures. A correlation was observed between the average fluorescence lifetime and the mechanical performance of CNC films, indicating that polymer chains with high mobility improved the strain and toughness. These studies demonstrated FLIM as a method to investigate polymer dynamics at the nanosecond timescale that can readily be applied to other composite systems.

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