4.8 Article

A Transferrable, Adaptable, Free-Standing, and Water-Resistant Hyperbolic Metamaterial

Journal

ACS APPLIED MATERIALS & INTERFACES
Volume 13, Issue 41, Pages 49224-49231

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsami.1c15481

Keywords

hyperbolic metamaterial; optoelectronics; laser action; quantum dot; foldable

Funding

  1. Featured Area Research Centre Program [108L9006]
  2. Ministry of Science and Technology in Taiwan [MOST 108-3017-F-002-002, MOST 108-2112-M-002-044]

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The study introduces a grating collageable HMM that enhances light-matter interaction and improves laser action through QDs and grating nanostructure. This HMM has various advantages and can be utilized in different applications.
Hyperbolic metamaterials (HMMs) have attracted significant attention due to the profound manipulation of the photonic density of states, resulting in the efficient optoelectronic devices with the enhanced light-matter interaction. HMMs are conventionally built on rigid large-size substrates with poor conformability and the absence of flexibility. Here, we demonstrate a grating collageable HMM (GCHMM), which is composed of eight alternating layers of Au and poly(methyl methacrylate) (PMMA) and PMMA grating nanostructure containing quantum dots (QDs). The QDs serve as a scattering gain medium performing a random laser action, and the grating nanostructure enhances the extraction of light from QDs. The GCHMM enhances laser action by 13 times, reduces lasing threshold by 46%, and increases differential quantum efficiency by 1.8 times as compared to a planar collageable HMM. In addition, the GCHMM can be retransferred multiple times to other substrates as well as provide sufficient protection in water and still retain an excellent performance. It also shows stable functionality even when transferred to a dental floss. The GCHMM, therefore, promises to become a versatile platform for foldable, adaptable, free-standing, and water-resistant optoelectronic device applications.

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