Journal
ACS APPLIED MATERIALS & INTERFACES
Volume 14, Issue 7, Pages 9525-9534Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsami.1c24306
Keywords
photocurrent spectroscopy; imaging; near-infrared; NIR; SWIR; nanocrystalline graphene; pyrolytic graphite; transfer matrix method
Funding
- German Research Foundation (DFG) [KR 3670/6-1, KR 3670/3-1]
- Helmholtz Research Programs Natural, Artificial and Cognitive Information Processing
- Materials Systems Engineering (MSE)
- Karlsruhe Nano Micro Facility (KNMF)
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In this study, photodetectors were fabricated from nanocrystalline graphene or graphite (NCG) with tailored layer thicknesses, achieving spectrally flat characteristics in the near-infrared to shortwavelength infrared region. The photodetectors exhibited homogeneous and unipolar biased photoresponse, with positive and negative photocurrents at the electrodes during short-circuit photoresponse.
Graphene, a zero-gap semiconductor, absorbs 2.3% of incident photons in a wide wavelength range as a free-standing monolayer, whereas 50% is expected for similar to 90 layers. Adjusting the layer number allows the tailoring of the photoresponse; however, controlling the thickness of multilayer graphene remains challenging on the wafer scale. Nanocrystalline graphene or graphite (NCG) can instead be grown with controlled thickness. We have fabricated photodetectors from NCG that are spectrally flat in the near-infrared to shortwavelength infrared region by tailoring the layer thicknesses. Transfer matrix simulations were used to determine the NCG thickness for maximum light absorption in the NCG layer on a silicon substrate. The extrinsic and intrinsic photoresponse was determined from 1100 to 2100 nm using chromatic aberrationcorrected photocurrent spectroscopy. Diffraction-limited hyperspectral photocurrent imaging shows that the biased photoresponse is unipolar and homogeneous across the device area, whereas the short-circuit photoresponse gives rise to positive and negative photocurrents at the electrodes. The intrinsic photoresponses are wavelength-independent, indicative of bolometric and electrothermal photodetection.
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