Copper content in anthropogenic sediments as a tracer for detecting smelting activities and its impact on environment during prehistoric period in Hexi Corridor, Northwest China

The Hexi Corridor of northwestern China was a principal axis of cultural interchange between eastern and western Eurasia during the prehistoric and historic epochs. Neolithic groups began dense settlements in Hexi Corridor after 4300 BP with millet crops and polychrome pottery from north China and bronze from Central Asia around 4000 BP accompanied by wheat, barley, and sheep. The impact of these activities on the environment during the late Neolithic and Bronze Age is not clearly understood. Therefore, we analyzed the Cu concentrations of samples collected within cultural layers of anthropogenic sediments from 17 Late Neolithic and Bronze Age sites located within the Hexi Corridor. The Cu content is reported in view of the archaeological and paleoclimatic research undertaken in the area. Our results enabled us to explore the variety of human impact on the environment before and after the introduction of bronze technology into Hexi Corridor. During 4300-4000 BP, Cu concentrations of the anthropogenic sediments were constrained within natural background values. However, from 4000 to 3400 BP, they increased substantially and far exceeded the natural background. The Cu concentrations then declined and remained above the natural background from 3000 to 2400 BP. Our work suggests that the introduction of copper melting technology led to human alteration of sediments' chemical properties in their surrounding environments in Hexi Corridor since 4000 BP; its intensity was closely related to human settlement density, which was further affected by climate change and livelihood transition in the area during Bronze period.