Journal
HETEROCYCLIC COMMUNICATIONS
Volume 22, Issue 6, Pages 333-337Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1515/hc-2016-0102
Keywords
aerobic oxidation; amines; enamines; Hinsberg reaction; sulfonyl chlorides
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Funding
- Soochow University [Q410900714]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
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2-Aminopyridine-3-sulfonyl chlorides undergo a reaction with tertiary amines in the presence of air to produce sulfonylethenamines. The 2-aminopyridine-3-sulfonyl chloride apparently plays a dual role in the process promoting the aerobic oxidation of the amine and electro-philically trapping the resulting enamine.
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