Journal
HETEROATOM CHEMISTRY
Volume 28, Issue 1, Pages -Publisher
WILEY-HINDAWI
DOI: 10.1002/hc.21352
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- CNRS
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The reaction between diethyl(alpha-acetoxymethyl) vinylphosphonate 1 and nitrogen- or sulfur-based nucleophiles occurs easily at room temperature in water as a solvent in the presence of 1,4-diazabicyclo [2.2.1]octane (DABCO) as an organocatalyst. This simple procedure enables the synthesis of nitrogen-and sulfur substituted vinylphosphonates, and also allows a convenient use of water-soluble salts as nucleophiles.
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