3.8 Article

A comparative evaluation of design factors on bubble column operation in photosynthetic biogas upgrading

Journal

BIOFUEL RESEARCH JOURNAL-BRJ
Volume 8, Issue 2, Pages 1351-1373

Publisher

Alpha Creation Enterprise
DOI: 10.18331/BRJ2021.8.2.2

Keywords

Biomethane; CO2 removal; Bubble column; Taguchi method; Microalgae

Categories

Funding

  1. Science Foundation Ireland (SFI) through the MaREI Centre for Energy, Climate, and Marine [12/RC/2302_P2, 16/SP/3829]
  2. Gas Networks Ireland through The Green Gas Innovation Group
  3. ERVIA
  4. IDL Pernod Ricard
  5. Environmental Protection Agency -Ireland [2018-RE-MS-13]
  6. Environmental Protection Agency Ireland (EPA) [2018-RE-MS-13] Funding Source: Environmental Protection Agency Ireland (EPA)

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This study quantitatively compared seven design factors and found that pH and liquid to gas flow rate were the most critical factors affecting biomethane composition, with effects on oxygen content up to 90%. pH and liquid to gas flow rate had the most impactful interactive effect.
Studies attempting to optimise photosynthetic biogas upgrading by simultaneous investigation of the bubble columnphotobioreactor setup have experienced considerable variability in results and conclusions. To identify the sources of such variation, this work quantitatively compared seven design factors (superficial gas velocity; liquid to gas flow rate (L/G) ratio; empty bed residence time; liquid inlet pH; liquid inlet alkalinity; temperature; and algal concentration) using the L16 Taguchi orthogonal array as a screening design of experiment. Assessments were performed using the signal to noise (S/N) ratio on the performance of CO2 removal (CO2 removal efficiency, CO2 absorption rate, and overall CO2 mass transfer coefficient) and O-2 stripping (O-2 concentration in biomethane and O-2 flow rate in biomethane). Results showed that pH and L/G ratio were the most critical design factors. Temperature and gas residence times had minimal impact on the biomethane composition. The interactive effect between pH and L/G ratio was the most impactful, followed by the interactive effects between superficial gas velocity and L/G ratio and pH on CO2 removal efficiency. The impact of L/G ratio, algal concentration, and pH (in that order of impact) caused up to a 90% variation in oxygen content in biomethane. However, algal concentration had a diminishing role as the L/G Using only the statistically significant main effects and interactions, the biomethane composition (CO2% and O-2 %) was predicted with over 95% confidence through regression equations for superficial gas velocity up to 0.2 cm/s. (C) 2021 BRTeam. All rights reserved.

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