4.8 Article

A dislocation-driven laminated relaxation process in Si1-xGex grown on Si (001) by molecular beam epitaxy

Journal

MATERIALS TODAY NANO
Volume 16, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.mtnano.2021.100140

Keywords

SiGe alloys; Pseudomorphic layer; Dislocation density; heterostructure; Strain analysis

Funding

  1. National Key R&D Program of China [2018YFA0306200, 2017YFA0303702]
  2. National Natural Science Foundation of China [51732006, 11890702, 11474158]
  3. Natural Science Foundation of Jiangsu Province, China [BK20151382]
  4. Fundamental Research Funds for the Central Universities and Innovative Technology Funds of NJU

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This study investigated the epitaxial growth of Si1-xGex thin films and observed a laminated relaxation process above a certain thickness, where the highly strained pseudomorphic layer could still be preserved even after relaxation. The anomalous relaxation phenomenon was attributed to a dislocation-driven relaxation mechanism, which could enhance the growth of highly mismatched heterostructure systems by manipulating dislocations.
Based on the successful epitaxial growth of Si1-xGex with a full spectrum of Ge content, we have grown a series of high-quality Si0.4Ge0.6 films with different thicknesses on Si (001) substrates using molecular beam epitaxy. A laminated relaxation process is observed in the Si1-xGex samples above a certain thickness. Strain analyses by X-ray diffraction and high-resolution transmission electron microscopy have shown that the highly strained pseudomorphic layer can be preserved even after the relaxation has occurred. We propose a dislocation-driven relaxation mechanism and attribute this anomalous relaxation phenomenon to the low growth temperature used. This study shows that the manipulation of dislocation can be an effective way to enhance the growth of a highly mismatched heterostructure system. (C) 2021 Elsevier Ltd. All rights reserved.

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