Journal
MATERIALS TODAY CHEMISTRY
Volume 20, Issue -, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.mtchem.2021.100455
Keywords
Organic-inorganic hybrid; Electrolyte; Deep eutectic solvents; Ionic conductivity
Funding
- A-STEP (Adaptable and Seamless Technology Transfer Program through targetdriven RD, JST, Japan)
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DE-SQ hybrids were synthesized by mixing quaternary-ammonium-containing SQ and urea derivatives, resulting in materials with low T-g, thermal stability, and high ionic conductivity. The type and feed ratios of urea derivatives were found to influence the formation and properties of the DE-SQs.
We report the synthesis of deep eutectic silsesquioxane hybrids (DE-SQs) by simple mixing of quaternary-ammonium-containing SQ and urea derivatives. Cationic SQ which was prepared by the hydrolytic condensation of a triethoxysilane precursor derived from 2-(dimethylamino)ethyl acrylate, followed by a quaternization reaction with methyl iodide, was used as a quaternary-ammonium-containing SQ component. Cationic SQ reacted with urea at a 1:2 M ratio at 80 degrees C for 48 h to yield a viscous DE-SQ (2Urea) liquid with a low glass transition temperature (T-g = -11 degrees C). Urea derivatives-1,3-dimethylurea (DMU) and 1,3-dimethylthiourea (DMTU)-were additionally used as hydrogen bond donors to form low-T-g DE-SQs. The thermal, physical, and ion-conductive properties of the DE-SQ family of organic-inorganic hybrids were investigated and characterized, and the influences of the nature of the urea derivative and their feed ratios on DE-SQ formation were evaluated. Among the DE-SQs developed in this study, DE-SQ(2Urea) and DE-SQ(2DMTU) achieved the highest ionic conductivity, with DE-SQ(2Urea) exhibiting 2.35 x 10(-6) and 6.63 x 10(-4) S cm(-1) at 25 and 75 degrees C, respectively, under anhydrous conditions. This is the first report on the synthesis of DE-SQs by simple mixing of two solids, wherein the resulting compounds exhibit low T-g, thermal stability, and characteristic ionic conductivity. The ability to incorporate unique DE units into the SQ structure facilitates the development of advanced organic-inorganic hybrid materials possessing a wide range of functions and applications. (C) 2021 Elsevier Ltd. All rights reserved.
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