4.4 Review

Differential dynamic microscopy for the characterization of polymer systems

Journal

JOURNAL OF POLYMER SCIENCE
Volume 60, Issue 7, Pages 1079-1089

Publisher

WILEY
DOI: 10.1002/pol.20210217

Keywords

differential dynamic microscopy; dynamic light scattering; polymer dynamics; polymer relaxation; scattering

Funding

  1. Associazione Italiana per la Ricerca sul Cancro [MFAG-22083]
  2. National Science Foundation, Directorate for Materials Research [DMR-1933487]

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DDM is a rapidly emerging approach that transforms a commercial microscope by combining real-space information with the powerful capabilities of conventional light scattering analysis. Analysis of a single microscope movie using DDM gives access to sample dynamics in a wide range of scattering wave-vectors, enabling contemporary polymer science experiments that would be difficult or impossible with standard light scattering techniques. Further applications of DDM to a variety of polymer systems are likely to be just around the corner, making DDM a tool of choice for modern experimental polymer scientists.
This review summarizes recent progress in investigating polymer systems by using Differential dynamic microscopy (DDM), a rapidly emerging approach that transforms a commercial microscope by combining real-space information with the powerful capabilities of conventional light scattering analysis. DDM analysis of a single microscope movie gives access to the sample dynamics in a wide range of scattering wave-vectors, enabling contemporary polymer science experiments that would be difficult or impossible with standard light scattering techniques. Examples of application include the characterization of polymer solutions and networks, of polymer based colloidal systems, of biopolymers, and of cellular motility in polymeric fluids. Further applications of DDM to a variety of polymer systems are suggested to be just behind the corner and it is thus likely that DDM will become a tool of choice of the modern experimental polymer scientists.

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