4.6 Article

Laminated graphene oxide membrane for recovery of mercury-containing wastewater by pervaporation

Journal

APPLIED WATER SCIENCE
Volume 11, Issue 7, Pages -

Publisher

SPRINGER HEIDELBERG
DOI: 10.1007/s13201-021-01453-x

Keywords

Laminated graphene oxide membrane; Wastewater treatment; Mercury removal; Pervaporation

Funding

  1. National Natural Science Foundation of China [21676210]
  2. Enterprise Joint Foundation of Shaanxi Science and Technology Department in China [2019JLM-23]

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The study successfully recovered Hg-containing wastewater using c-GO-PEI layered membrane, demonstrating high rejection rates and flux. The membrane showed excellent antifouling property, with flux largely recoverable after simple washing.
Mercury (Hg) is a toxic heavy metal contaminant and has very harmful effects for human health. In this work, Hg-containing wastewater with Hg concentration of 6.36 ppb and 9.4 ppb were recovered with polyethylenimine (PEI) cross-linked graphene oxide (GO) layered membrane (c-GO-PEI) by pervaporation. The influence of ionic type, the concentration of Hg and the feed temperature were investigated. The c-GO-PEI exhibited not only high rejection for salts (> 99.97%), Hg (77.5-100%) and non-purgeable organic carbon (NPOC) (67.3-90.8%) but also high flux (30.30 kg center dot m(-2)center dot h(-1)) to treat with the wastewater. In addition, the flux could be largely recovered after simple washing, indicating the excellent antifouling property of the membrane.

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