4.7 Review

Carbon Quantum Dots for Energy Applications: A Review

Journal

ACS APPLIED NANO MATERIALS
Volume 4, Issue 7, Pages 6515-6541

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsanm.1c01372

Keywords

carbon quantum dots; energy applications; supercapacitors; photovoltaics; hydrogen evolution reaction; oxygen evolution reaction

Funding

  1. Ministry of Science and Technology of the Republic of China [MOST 108-2218-E-011-017-MY3, 110-2113M-011-003]
  2. Taiwan Building Technology Center from The Featured Areas Research Center Program by Ministry of Education in Taiwan

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Carbon quantum dots are a promising class of carbon nanomaterials with advantages of low toxicity, environmental friendliness, photostability, and easy synthesis. They are currently mainly applied in energy fields such as supercapacitors, lithium-ion batteries, and photovoltaics. The future challenge lies in improving their performance and reducing cost.
Carbon quantum dots (CQDs) are a class of carbon nanomaterials that have recently gained recognition as current entrants to traditional semiconductor quantum dots. CQDs have the desirable advantages of low toxicity, environmental friendliness, low cost, photostability, favorable charge transfer with enhanced electronic conductivity, and comparable easy-synthesis protocols. This review examines the advancements in CQD research and development, with a focus on their synthesis, functionalization, and energy applications. Initially, various synthesis methods are discussed briefly with pros and cons. Herein, first top-down methods including the arc-discharge technique, laser ablation technique, plasma treatment, ultrasound synthesis technique, electrochemical technique, chemical exfoliation, and combustion were discussed briefly. The later section presents bottom-up (microwave synthesis, hydrothermal synthesis, thermal pyrolysis, and metalorganic framework template-assisted approach) and waste-derived CQD synthesis methods. The next section is focused on the energy applications of CQDs including supercapacitors, lithium-ion batteries, photovoltaics, hydrogen evolution reaction and oxygen evolution reaction. Finally, challenges and future perspectives in this exciting and promising area are presented.

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